Non-local real-space analysis of chiral optical signals
نویسندگان
چکیده
A spatially non-local response tensor description of linear chiral signals such as circular dichroism is developed. By working directly with the vector potential rather that the electric and magnetic fields, we recast the signals in terms of correlation functions of charge and current densities and avoid the tedious expansion in multipoles.
منابع مشابه
Theoretical study of magnetic susceptibility and optical activity of small molecules containing one chiral center
In the first part of this work, correlation between optical activity and elements of magnetic susceptibility tensor (MST) for five classes of model small molecules containing a single chiral center has been studied using quantum computational techniques at DFT-B3LYP level of theory with 6-311G basis set. Several molecular properties are used to reduce the MST elements prior to the examination o...
متن کاملOptical Chirality Enhancement in Twisted Arrays of Plasmonic Nano-rods
An important property of electromagnetic fields, which arises from the interaction between fields and chiral molecules, is called optical chirality. By enhancing this field property, while maintaining constant input power, we are able to increase absorption of circularly polarized light by chiral molecules of a certain handedness. This enhancement is achieved through the use of achiral plasmoni...
متن کاملLow Decision Space Means No Decentralization in Fiji; Comment on “Decentralisation of Health Services in Fiji: A Decision Space Analysis”
Mohammed, North, and Ashton find that decentralization in Fiji shifted health-sector workloads from tertiary hospitals to peripheral health centres, but with little transfer of administrative authority from the centre. Decisionmaking in five functional areas analysed remains highly centralized. They surmise that the benefits of decentralization in terms of services and outcomes will be limited....
متن کاملComputational study in Regioselectivie Synthesis of New Spiro-oxindolopyrrolidines
One-pot, four-component procedure for the synthesis of a small library of new chiral spiro- oxindolopyrrolidines with high regio-, diastereo- (>99:1 dr), and enantioselectivity (up to 80% ee) is described. In this process, the regio- and stereochemical 1,3-dipolar cycloaddition of azomethine ylides, which were generated insitu by the reaction of isatin derivatives and sarcosin,with optically ac...
متن کاملAttenuation of spatial aliasing in CMP domain by non-linear interpolation of seismic data along local slopes
Spatial aliasing is an unwanted side effect that produces artifacts during seismic data processing, imaging and interpolation. It is often caused by insufficient spatial sampling of seismic data and often happens in CMP (Common Mid-Point) gather. To tackle this artifact, several techniques have been developed in time-space domain as well as frequency domain such as frequency-wavenumber, frequen...
متن کامل